Rio de Janeiro: Defending Olympic champion and world number one Serena Williams suffered a shock third round defeat at the hands of Ukraine`s Elina Svitolina on Wednesday at Olympic Tennis Centre, Rio de Janeiro.


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Serena, winner of 22 Grand Slam singles title, failed to produced her routine game and lost the match in straight sets, 6-4, 4-3 in one hour and 12 minutes.


Her elder sister Venus had already crashed out of the singles competition. Besides, the the Williams sisters suffered their first defeat as a doubles team at Olympics yesterday.


Svitolina, ranked 20 in the world, will play former world number one two-time Wimbledon champion Petra Kvitova of Czech Republic in tomorrow's quarter-final.


Kvitova is a also a time-time quarter-finalist at Olympics.