Washington: The Southwest Research Institute scientists have increased the speed and accuracy of a laboratory-scale instrument for determining the age of planetary specimens onsite. The team is progressively miniaturising the Chemistry, Organics and Dating Experiment (CODEX) instrument to reach a size suitable for spaceflight and lander missions.


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"In situ ageing is an important scientific goal identified by the National Research Council`s Decadal Survey for Mars and the Moon as well as the Lunar and Mars Exploration Programme Analysis Groups, entities responsible for providing the science input needed to plan and prioritize exploration activities," said SwRI Staff Scientist Dr F Scott Anderson, who is leading CODEX development.


"Doing this onsite rather than trying to return samples back to Earth for evaluation can resolve major dilemmas in planetary science, offers tremendous cost savings and enhances the opportunities for eventual sample return," Anderson added. 


CODEX will be a little larger than a microwave and include seven lasers and a mass spectrometer. In situ measurements will address fundamental questions of solar system history, such as when Mars was potentially habitable. CODEX has a precision of +-20-80 million years, significantly more accurate than dating methods currently in use on Mars, which have a precision of +-350 million years.


"CODEX uses an ablation laser to vaporise a series of tiny bits off of rock samples, such as those on the surface of the Moon or Mars," said Anderson, who is the lead author of a CODEX paper published in 2020.


Anderson further noted, "We recognise some elements directly from that vapour plume, so we know what a rock is made of. Then the other CODEX lasers selectively pick out and quantify the abundance of trace amounts of radioactive rubidium (Rb) and strontium (Sr). 


An isotope of Rb decays into Sr over known amounts of time, so by measuring both Rb and Sr, we can determine how much time has passed since the rock formed. "While radioactivity is a standard technique for dating samples on Earth, few other places in the solar system have been dated this way. Instead, scientists have largely constrained the chronology of the inner solar system by counting impact craters on planetary surfaces.


"The idea behind crater dating is simple: the more craters, the older the surface. It is a little like saying that a person gets wetter the longer they have been standing out in the rain. It is undoubtedly true. But as with the falling rain, we do not really know the rate at which meteorites have fallen from the sky," said Dr Jonathan Levine, a physicist at Colgate University, who is part of the SwRI-led team.


"That is why radioisotope dating is so important. Radioactive decay is a clock that ticks at a known rate. These techniques accurately determine the ages of rocks and minerals, allowing scientists to date events such as crystallisation, metamorphism, and impacts," Levine added.


The latest iteration of CODEX is five times more sensitive than its previous incarnation. This precision was largely accomplished by modifying the sample`s distance from the instrument to improve the data quality. The instrument also includes an ultrafast pulsed laser and improved signal-to-noise ratios to better constrain the timing of events in solar system history.


"We are miniaturising the CODEX components for field use on a lander mission to the Moon or Mars. Developing compact lasers with pulse energies comparable with what we currently require is a considerable challenge, though five out of the seven have been successfully miniaturised. These lasers have a repetition rate of 10 kHz, which will allow the instrument to acquire data 500 times faster than the current engineering design," Anderson said.


The CODEX mass spectrometer, power supplies, and timing electronics are already small enough for spaceflight. Instrument components are being enhanced to improve ruggedness, thermal stability, radiation resistance, and power efficiency to endure launch and extended autonomous operations in alien environments.