London: Scientists have come up with a new technique that can use sunlight and water to make hydrogen tirelessly.
According to a report in New Scientist, the technique, developed by Thomas Nann and colleagues at the University of East Anglia in Norwich, UK, can convert 60 per cent of sunlight energy absorbed by an electrode into the inflammable fuel. To generate the gas, Thomas Nann and colleagues at the University of East Anglia in Norwich, UK, dip a gold electrode with a special coating into water and expose it to light. Clusters of indium phosphide 5 nanometres wide on its surface absorb incoming photons and pass electrons bearing their energy on to clusters of a sulphurous iron compound.
This material combines those electrons with protons from the water to form gaseous hydrogen.
A second electrode – plain platinum this time – is needed to complete the circuit electrochemically.
Organic molecules have been used before to perform the same feat. But, they are quickly bleached by the sunlight they are collecting, rendering them inefficient after a few weeks.
The inorganic materials used in the University of East Anglia’s system are more resilient.
Their first generation proof of concept is “a major breakthrough” in the field, thanks to its efficiency of over 60 per cent and ability to survive sunlight for two weeks without any degradation of performance.
“In fact, the 60 per cent figure is probably a worst-case scenario. This is still a preliminary study,” said Nann.
That high efficiency is largely thanks to the indium phosphide clusters being better at grabbing photons than organic molecules.
“Think of them as a butterfly net for catching photons,” said Nann.
By the standard measure of the probability that a material will absorb a photon that hits it, each cluster is 400 times better at netting photons than organic molecules used in previous systems.
“That’s why it works so well,” said Nann.
He and colleagues now plan to refine the system, including lowering the cost by making it with less expensive materials.
First Published: Saturday, February 13, 2010, 18:35